Drop a dirty penny into a glass of Coke. If you examine the penny after a
week, Abraham Lincoln’s head will be gleaming. The carbonic acid in the cola
has dissolved the organic grime on the copper-plated coin. It’s a
science-class experiment many of us will remember from childhood. Now
consider that the ocean is becoming corrosive, like Coke.
The phenomenon is called ocean acidification, and, like climate change, it
is a result of increasing carbon dioxide (CO2) emissions. The
oceans have absorbed about one third of the CO2 released into the
atmosphere by humans over the past 200 years, and that is changing the
waters’ chemistry. The oceans are not fizzing like that glass of Coke--the
chemical change is not that extreme--but they are becoming more acidic, with
ominous consequences. A shift in the pH balance of seawater is under way,
and it threatens shell-building creatures, corals, fisheries such as salmon,
oysters, mussels, and sea urchins, and entire marine ecosystems.
The chemical reactions involved in acidification are well understood. There
is also no controversy over the fact that acidification is happening on a
global scale. And what can be done to slow it down is simple from a
scientific view: eliminate all sources of human CO2 emissions,
immediately. Even if it were possible for this to occur, however, the harm
will likely continue. Enough CO2 may have already entered the
ocean to cause hundreds of years of damage to millions of years’ worth of
evolutionary progression.
Acidity is measured on a pH scale, which ranges from 0 (strong acid) to 14
(strong base), with pure water a neutral 7. Like the seismic scale for
earthquakes, the pH scale is logarithmic, so each additional 0.1 is in fact
an increase of 30 percent. Depending on the marine habitat and depth,
seawater can range in pH from 7.5 to 8.4, so it’s slightly basic. When CO2 dissolves in seawater, it forms carbonic acid. A few chemical reactions
later, extra hydrogen ions are released; it is those ions that lower the pH
level, making the water more acidic.
Ken Caldeira, an ocean acidification researcher at the Carnegie Institution
for Science, recently described a demonstration experiment simple enough for
a middle-school science fair. First, place a beaker of water inside an
airtight bell jar and start pumping CO2 into the jar. The water
begins to absorb the gas as the bell jar fills. A few dips of litmus paper
into the water over a short amount of time will give pH readings. "You can
test the pH of the water and watch it shift," Caldeira said.
Unlike pure water, seawater contains many dissolved ions that help maintain
a stable pH, including carbonate ions. The more CO2 is forced
into the water, the more carbonate ions are needed to keep the system
balanced. If seawater were used in Caldeira’s experiment, it would take
longer to see the pH change because of the carbonate ions--at first. Once
those carbonate ions run out, however, the pH would plummet and the water
would acidify. In the oceans, whatever carbonate ions are used to
equilibrate the seawater chemistry are no longer available for corals and
other animals to build their protective shells.
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